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1. Rubidium has a heat of vaporization of 69.0 kJ/mol at its boiling point (686oC). For the process Rb(l)-->Rb(g) at 1 atm and 686oC. Calculate the value of DSsurroundings.
0
69.0 kJ/mol
71.9 J/K mol
61.0 kJ/mol
-71.9 J/K mol

2. Liquid sample A freezes at -8°C. Determine the signs of DH, DS, and DG.
+,+,+
+,-,-
-,-,-
-,+,0
None of the above

3. For the gas sample B, this reaction is endothermic: B-->2B. The reaction is:
always spontaneous
only at high temperatures
only at low temperatures
never spontaneous
none of the above

4. Choose the correct statement.
Exothermic reactions are always spontaneous
High temperature ensures a spontaneous reaction
Free energy is independent of temperature
A reaction with negative DS cannot be spontaneous
none of the above

5. DS for the universe is:
always positive
sometimes positive
always negative
sometimes negative
constant

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