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1. Which of the following will be true when a pure substance in liquid phase freezes spontaneously?
DG, DH, and DS are all positive
DG, DH, and DS are all positive

2. Rubidium has a heat of vaporization of 69.0 kJ/mol at its boiling point (686oC). For the process Rb(l)-->Rb(g) at 1 atm and 686oC. Calculate the value of DSsurroundings.
0
69.0 kJ/mol
71.9 J/K mol
61.0 kJ/mol
-71.9 J/K mol

3. A change of state occurs within a system and produces 64.0 kB of heat which is transferred to the surrounding at a constant pressure and a constant temperature of 300K. For this process DSsurroundings is:
64.0 kJ
-64.0 kJ
-213 J/K
213 J/K
none of these

4. Which of the following statements is always TRUE for a spontaneous process?

I. DSsys > 0
II. DSsurr > 0
III. DSuniv > 0
IV. GSsys > 0


I
III
IV
I and III
III and IV

5. Which of the following favors a negative DG?
increasing energy and increasing entropy
lowering energy and increasing entropy
increasing energy and decreasing entropy
lowering energy and decreasing entropy
none of the above

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