| Aldehyde Nomenclature: The aldehyde fucntional group is a -CHO which looks like this:
The carbonyl carbon (the one connected O and H) is always carbon 1, unless there is a carboxylic acid group on the other end. Hence, the numbers aren't mentioned when mentioning aldehydes. In order to designate a molecule as an aldehyde, you must drop the "ending" (-ane from an alkane) and add "al" (for aldehyde). Name this molecule:
That would be butanal. Now, try this one:
This would be 3-butenal. Try this one:
2-ethylhex3-ene-4-yne-al. That was a toughie. When the aldehyde isn't the highest priority group, the prefix formyl- is used. Let's try this one:
This would be formylpentanoic acid. No need to number, because both the carboxylic and aldehyde functional groups are located at the end, and there are ony two ends :) Cyclic Aldehydes For cyclic aldehydes, the suffix -carbaldehyde is added to the ring name. Let's check an example:
Cyclopentanecarbaldehyde. Easy, isn't it? Remember that whatever carbon the -CHO group is on, that is carbon-1. |