| Nuclear Chemistry By Hao Zhang Charges of Elemental Components Of the three elemental components, a proton has a positive charge, a neutron has a neutral charge, and the electron has a negative charge. The atomic number (designated by the symbol Z) represents the number of protons in the nucleus. In an element, which never has a charge, the number of protons equals the number of electrons. The mass number (A) is the sum of neutrons and protons in the nucleus. Therefore, A - Z equals the number of neutrons in a nucleus.
Typical Nuclide(where X equals any element): Kinetic stability- the likelihood of a nucleus to change into a more stable state. Thermodynamic stability- A comparison of the potential energy of the nucleus to the sum of the potential energy of its protons and neutrons. A nuclide becomes more stable through radioactive decay. Alpha particle (a ) decay-emission of helium particle:
Beta particle (b -)decay- emission of an electron:
Positron (b +) emission-a positively charged electron:
Electron capture (b -)-a gaining of electrons:
When a positron and an electron are combined, the result is 2 gamma rays. This process is called annihilation.
Gamma ray (g )-high energy photons that accompany nuclear decays and particle reactions. Since they have neither mass nor charge, they are usually disregarded in equations.
*Gamma rays are only produced in specific reactions. Some nuclides exhibit a "zone of stability" where radioactive decay does not take place.
All radioactive decay reactions are 1st order. For a 1st order reaction:
The half-life equation for a nuclear reaction
Nuclear transformation is the conversion of one element to another. Two methods of nuclear transformation: 1. Cyclotron - A particle is accelerated through a particle accelerator and is
penetrated into the nucleus. Fission isthe splitting of a heavy nuclide into two smaller nuclides. Excess neutrons and energy is produced in the reaction. For a chain reaction, the emitted neutrons split nearby nuclides that produce a self-sustaining reaction. Types of Fission reactions Fusion-combining two smaller nuclides to form one heavy nuclide. During radioactive decay, the nuclides emit radiation.
Rads (radiation absorbed dose) -measurement of radiation 1 rad=10-2J / kg tissue Rem (roentgen equivalent for men)-measures both dosage of radiation and its effectiveness in the environment. 1 rem=#of rads * RBE RBE-the effectiveness of radiation to cause biological damage. |