| Conjugated Dienes Tutorial Since you already know how to name alkenes, this tutorial will focus more on the concepts of dienes. There are three types of conjugated dienes:
Delocalization- existence of p electron cloud extends over four carbons (in a conjugated diene), opposed to two in a normal -ene. This is important because the delocalization means that the carbon has more electrons to share amongst itself, which lowers energy and makes the molecule more stable. Resonance theory - states whenever a molecule or ion can be represented by two or more structures that differ only in the position of the electrons, there are three implications: (I shamelessly stole these off of my organic chem book)
This is a reaction where the bromine is removed from an alkene. The removal of bromine creates a carbocation (since the bromine stole the electron pair that originally kept the carbon neutral). A carbocation is a carbon with a positive charge. As the image above demonstrates, the p bonds from the neighboring carbon can "shift" over to the carbocation. However, this leaves the other carbon with a positive charge. Eventually, you will add something to get rid of that charge. This is resonance. Later on, in the aromatics chapter, you will see more examples of resonance. |